Try to place baby at the breast as soon as possible after birth. Ideally, this will happen right in the delivery room. Ensure that your practitioner will allow you to nurse in the birthing or delivery room if all goes normal.
Babies only minutes old will often crawl up to the breast from the mother's abdomen, and start breastfeeding all by themselves. This process may take up to an hour or longer, but the mother and baby should be given this time together to start learning about each other. Babies who "self-attach" run into far fewer breastfeeding problems. This skin-to-skin contact will also help keep the child warm.
Adapted from: http://www.pregnancy-info.net/breastfeeding_tips.html